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I have naturally started tinkering with these emulsions (by assigning a student to studying this type of emulsions). Oil-in-water Pickering emulsion refers to an emulsion where droplets of oil are dispersed in water as the continuous phase. I find these emulsions interesting, since it is not completely clear to me what physical parameters are responsible for the apparent meta-stability of these emulsions. Proteins, polysaccharides, and their composite particles can be used as good particle. These types of emulsions are known as “Pickering” emulsions and are a type of particle super-assembly. Pickering emulsion, which is an emulsion stabilized by solid particles, offers a wide range of potential applications because it generally provides a more. High internal phase Pickering emulsion (HIPPE) is a type of emulsion stabilized by solid particles irreversibly adsorbed on an interfacial film, and the volume fraction of the dispersed phase () is larger than the maximum packing volume fraction ( max). When you shake oil and vinegar together (with a speck of mustard) you form a semi-stable vinaigrette, which is stabilized by small insoluble mustard particles. The milk-fat droplets in homogenized milk are stabilized by small protein-covered calcium particles that adsorb to the fat/whey interface. Particle stabilized emulsions are found in many (tasty) applications. Can we now manipulate these particles and have them assemble into larger particles? This is a form of nano-assembly, which is controlled by a mini-emulsion template. So, we make polymer nano-capsules by enclosing a 100 nm droplet of an oil solution within a 10 nm thick polymer shell. Here, we review recent findings concerning Pickering emulsions, with a particular focus on how the nanoparticles morphology (i.e., cube, ellipsoid, nanosheet, sphere, cylinder, rod, peanut) influences the type and stability of such emulsions, and their current applications in different fields such as antibacterial activity, protein recognition, catalysis, photocatalysis, and water purification.HIERARCHICAL ASSEMBLY OF POLYMER CAPSULES Moreover, the nanoparticle morphology strongly influences Pickering emulsion stability as well as the potential utilization of such emulsions. Therefore, they can be considered attractive components for various uses, such as photocatalysis and the preparation of new materials. Furthermore, Pickering emulsions show higher stability, lower toxicity, and stimuli-responsiveness, compared with emulsions that are stabilized by surfactants. In the past 10 years a new application has emerged in the field of catalysis to use them as vehicles to carry out catalytic reactions, allowing a more environmentally friendly process with high conversions and selectivities and important advantages for catalyst recovery. For emulsions with a higher concentration of nanoparticles, a larger number of polymeric nanoparticles could be used to cover the oilwater interface and then stabilize the emulsions. S2, as the concentration of micellar aggregates increased, the droplet size of the Pickering emulsion decreased. In contrast to classical emulsions, in Pickering emulsions, solid microparticles or nanoparticles that localize at the interface between liquids are used as stabilizers, instead of surfactants, to enhance the droplet lifetime. Particle-stabilised or Pickering emulsions are versatile systems. The Pickering emulsions were prepared by homogenizing a mixture of toluene and deionized (DI) water at 15 000 rpm for 120 s with different emulsifier concentrations at pH 2. ![]() In recent years, Pickering emulsions and their applications have attracted a great deal of attention due to their special features, which include easy preparation and enhanced stability. Chrome does not have any of these issues in the last few weeks of my usage. The difference is massive.Įdge feels slow in terms of the smoothness of opening menus, loading settings, loading extensions, typing lag on screen, etc. I have been switching back and forth between Chrome and Edge for over a month now. ![]() I am talking about browser responsiveness. I am not talking about the download speed. You install it, disable some Google stuff and you're good to go. This is why Chrome shines, it keeps only the most "used" features and it's a simple experience. What I'm trying to say is that for users who prefer a "simple" browsing experience, most of the features are just unneeded. + some other additional features from Privacy settings menu. Homepage - I disable the news I like to keep only the most visited sites + the backgrounds Yet another one, I understand that this is a MS product and it's ok, but If I change the search Engine to another one, I still have Bing remains (Bing search in InPrivate mode, Search Bing in Sidebar, Search Bing in Sidebar in installed "apps" etc.)īasically Edge is a good browser but not for everyone, I highly customize it and disable some of the features: ![]() One downside about Edge is that it's getting a little bit bloated - especially when the user does not customize it at all (fresh install).Īnother down-side - The Right Click context menu is just getting ridiculously big ![]() Edge makes better use of screen space - for example the Tabs section - the UI in general is larger which depends on tastes, but I like it Smooth scrolling in Edge is just perfect Edge has more features (good PDF reader, startup boost, better integration with Windows, Vertical Tabs, Collections etc.) Speed-wise, they are basically the same, with Edge being a little bit "smoother". ![]() Libpq is the native C client library for connecting to PostgreSQL. Install and require the sequel gem, and create a database connection:ĭB = nnect("postgres://localhost/")ĭownload and install the PostgreSQL JDBC driverĬonnect to the JDBC URL jdbc:postgresql://localhostįor more information see the official PostgreSQL JDBC documentation. Install and require the datamapper and do_postgres gems, and create a database connection:ĭtup(:default, "postgres://localhost/") Install the activerecord gem and require 'active_record', and establish a database connection:ĪctiveRecord::Base.establish_connection("postgres://localhost/") In config/database.yml, use the following settings: To install the pg gem, make sure you have set up your $PATH correctly (see Command-Line Tools), then execute the following command: sudo ARCHFLAGS="-arch x86_64" gem install pg Rails When using the Flask-SQLAlchemy extension you can add to your application code:Īpp.config = 'postgresql://localhost/'Įngine = create_engine('postgresql://localhost/') "ENGINE": "django.db.backends.postgresql_psycopg2", In your settings.py, add an entry to your DATABASES setting: To connect to a PostgreSQL server with Python, please first install the psycopg2 library: Or the pg_connect() functions (procedural): Prepare("SELECT datname FROM pg_database") Įcho "". We recommend MAMP for an easy way to install a current version of PHP that works. The version included with macOS doesn't support PostgreSQL. To connect from PHP, make sure that it supports PostgreSQL. Here’s how to connect to PostgreSQL from popular programming languages and frameworks: PHP How to connectĪfter your PostgreSQL server is up and running, you’ll probably want to connect to it from your application. ![]() However, it doesn’t have the extensive feature set of pgAdmin, and it’s a commercial app rather than open source.Īside from those two options, there are a lot more to choose from! Check the documentation for a list of amazing Mac apps for PostgreSQL. We put a lot of effort into making it a joy to use. It’s made by the same people that maintain Postgres.app, and we think you’ll like it! Postico on the other hand, is a very modern Mac app. The only downside is that the cross-plattform UI really doesn’t live up to the expectations of a native Mac app. ![]() It has support for almost every feature in PostgreSQL. PgAdmin 4 is a feature rich open source PostgreSQL client. Postgres.app includes psql, a versatile command line client for PostgreSQL.īut it’s not the only option there are plenty of great graphical clients available for PostgreSQL. We also have instructions for upgrading from older versions of Postgres.app. If you have previously installed PostgreSQL using homebrew, MacPorts, the EnterpriseDB installer, consider removing other PostgreSQL installations first. ![]() NOTE: These instructions assume that you’ve never installed PostgreSQL on your Mac before. If you’d rather use a graphical client, see below. To connect directly from the command line, type psql. To connect with psql, double click a database. If you don't move Postgres.app to the Applications folder, you will see a warning about an unidentified developer and won't be able to open it.Ĭlick "Initialize" to create a new serverĬonfigure your $PATH to use the included command line tools (optional): sudo mkdir -p /etc/paths.d &Įcho /Applications/Postgres.app/Contents/Versions/latest/bin | sudo tee /etc/paths.d/postgresappĭone! You now have a PostgreSQL server running on your Mac with these default settings: Host Installing Postgres.appĭownload ➜ Move to Applications folder ➜ Double Click Postgres.app can install minor updates automatically, so you get bugfixes as soon as possible. You never need to touch the command line to use it – but of course we do include all the necessary command line tools and header files for advanced users. Postgres.app has a beautiful user interface and a convenient menu bar item. It includes everything you need to get started,Īnd we’ve even included the popular extension PostGIS for geo data. Postgres.app is a full-featured PostgreSQL installation packaged as a standard Mac app. ![]() ![]() i am very up set at this company, this year none of my friends will be getting their usual perfumes,lotions etc!!! from me or at least from this company.you have LOST A VERY FAITHFUL CUSTOMER. I had to call Customer service twice, wondering where my order was. so DOnot use the samples there because obviously the employees donot clean or wash their hands. 761 reviews for Bed Bath & Beyond, 3.6 stars: Dirty laundry is their business. i would be more than happy to put up the picture of this ugly cold sore and let the customers know how UN-sanitary this store really is. i would like a district manager to get ahold of me i have left my number. i am very appalled no one has cared enough on how disqusting this cold sore has spread. i went back a couple days later and the same tube of spearmint gloss was still there for sampling. If you would like to contact them here is their email:. i called the store asked to speak to the manager, the manager didn't even care about my situation i asked her for her district managers name and number and she said oh i don't have it!!! she was very unprofessional. Bed Bath and Beyond got this email from me today. I was at the stire at desert sky mall, i sampled the spearmint lipgloss with the lil sample spatula stick, and the next day i woke up with a cold sore. Bed Bath & Beyond’s popular 20-off coupons have conditioned the customer to expect markdowns, Amlani said, which can be dangerous during a time when a company is trying to boost its sales. The company has voluntarily provided company contact details and is considered to be responsive to customer complaints. I have been trying to get a hold of a district manager here in phoenix,az. Bed Bath & Beyond Formed in 1971, the stores sell goods primarily for the bedroom and bathroom, as well as kitchen and dining room. Wegner specifically to question him about the changes he was already seeing in the SSPX. Jürgen Wegner, District Superior of the SSPX's United States of America District. Girouard say in the sermon? He shares his October (2013) conversation with Fr. Girouard states here – as he has been doing since 2013 – have been publicly negated or proven false by the SSPX. ![]() It is simply to show that changes were made in the SSPX in order to satisfy demands of Rome. I want to repeat that this is not about this priest or that one. I myself had not heard about the "rebranding" of the SSPX, which explains what I have seen, a softening of position from the heads. ![]() I thought it was worth passing on to you and your readers as a kind of update on the situation. Joseph Defender of the Church in Canada, he provides a good résumé of what has taken place in the last five years. Patrick Girouard, a well-established priest in the SSPX who left it in 2013 because he was convinced Bishop Fellay was making that compromise. I recently received a link to a Corpus Christi sermon (2018) delivered by Fr. I don't follow the daily gossip among traditionalists and conservatives, but have appreciated what I have gained from your site. I have always believed it is good to make these facts known to the general public. ![]() This compromise would follow the general lines of Ecclesia Dei Commission, which were accepted by other traditionalist/conservative groups: that is, acceptation of the Novus Ordo Mass, of Vatican II read in a conservative way, to not criticize the Pope, to be in accord with the local Bishop, to not discuss publicly these items. I have heard you criticized by SSPX followers for exposing facts that confirm a SSPX compromise with the Vatican. ![]() When it comes to steak, this spot offers signature Prime Steak Burgers with 8 oz USDA Prime ground sirloin with options like “The Franklin Bic Mac” burger, The Jersey burger, and the “Bacon & Egger” burger. While they have been known to switch up the flavors, their current calamari choices include Asian, Balsamico, Buffalo, and Traditional. Try out their Filet Mignon Vegetable Spring Roll, Filet Mignon Burgers, or the Filet Mignon Carpaccio.ĭetails: The folks at Franklin Steakhouse are big fans of calamari, so much so that it has its own menu. Not to repeat too much, but the Filet Mignon is so popular, it appears on the appetizers menu as well. They also have a Surf and Turf option combining their 12 oz Filet Mignon with a 6 oz Lobster Tail. Popular picks include the 12 oz Filet Mignon and 32 oz Gotham Bone-in Rib for two. They specialize in dry-aged, New York-style steaks, from Sirloin to Rib Steak. They can also handle large groups for special occasions.ĭetails: Edward’s is housed inside a renovated historic building from the 1800s. Locals say Don Pepe is a great place for date night which may or may not have anything to do with their extensive wine list that includes both Spanish and Californian options. Other meat entrees include T-Bone Steak, Filet Mignon, and Boneless Shell Steak. ![]() In addition to favorites like Veal Chops and Surf and Turf, they Queen and King size sirloins. (A common style of domestic architecture during this time period.) As for steak options, they specialize in T-Bone, Braised Short Ribs, NY Strip, and Grilled Marinated Skirt Steak but they also have Filet Mignon, baby back ribs, and a number of veal, lamb, pork, and chicken dishes.ĭetails: Don Pepe claims to be home to the best Porterhouse steak in New Jersey but they serve plenty of other steak and meat options as well. In fact, it is one of the area’s only remaining examples of Federal Greek Revival architecture. But the building itself actually dates back even further, as far as the 1850s. But take note, they only serve this item in limited quantities every day.ĭetails: The Brick House has been serving top notch steak in Bergen County for more than 50 years. In particular, we recommend the Red Hawk Steak Sandwich with sliced Filet Mignon, fresh mozzarella, roasted red peppers, and balsamic dressing. Other popular picks on the menu include their half-pound burgers and signature sandwiches, each served with steak fries. More info: Click here to visit their website | Follow them on Instagram | Click to give them a call.ĭetails: This casual American steakhouse is known for its 24 oz Delmonico Steak (a more affordable alternative to Ribeye) which they serve with a choice of baked potato, mashed potatoes, or fries. Why I like it: Dino & Harry’s will often feature live music, including a live piano player during dinner. As for the drink menu, they offer beer, cocktails, gin, mules, rum, scotch, tequila, vodka, whiskey, wine, and more. Besides the atmosphere, locals love the menu, which includes a robust selection of steaks including Filet Mignon (and a Petit 6 oz option), Porterhouse, Rib eye, and Sirloin (both 16 oz and 22 oz). To this day, most of the architectural details remain the same the restaurant even houses a 150-year-old clock.
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